Creating a bibliography from more than one EndNote library for document is possible but not recommended for large documents as various problems may occur.

There may be duplicate records in each library and EndNote will not be able to format a reference with two different identification numbers. What may be {Smith 1987, #345} in one library may be {Smith 1987, #200} in another.

Its best to merge separate libraries before inserting temporary EndNote citations

To Import one EndNote library into another

You can also simply copy references from one library to another